application of dimeric ortho-palladated complex of 2-methoxyphenethylamine in the heck coupling reaction
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abstract
the application of the [pd{c6h3(ch2ch2nh2)-4-ome-5-κ2-c,n}(μ-br)]2 complex of 2-methoxyphenethylamine in the heck coupling reaction was considered under both conventional and microwave irradiation conditions, and their results were compared. this complex is an efficient, stable and non-sensitive to air and moisture catalyst for the vinylation of substituted aryl halides with different electronic properties. the cross-coupled products were produced in good to excellent yields using a catalytic amount of this complex in n-methyl-2-pyrrolidone (nmp) at 130 °c. in comparison to conventional heating conditions, the reactions under microwave irradiation gave higher yields in shorter reaction times.
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Application of dimeric ortho-palladated complex of 2-methoxyphenethylamine in the Heck coupling reaction
The application of the [Pd{C6H3(CH2CH2NH2)-4-OMe-5-κ2-C,N}(μ-Br)]2 complex of 2-methoxyphenethylamine in the Heck coupling reaction was considered under both conventional and microwave irradiation conditions, and their results were compared. This complex is an efficient, stable and non-sensit...
full textApplication of dimeric ortho-palladated complex of 2-methoxyphenethylamine in the Heck coupling reaction
The application of the [Pd{C6H3(CH2CH2NH2)-4-OMe-5-κ2-C,N}(μ-Br)]2 complex of 2-methoxyphenethylamine in the Heck coupling reaction was considered under both conventional and microwave irradiation conditions, and their results were compared. This complex is an efficient, stable and non-sensit...
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full textSuzuki-Miyaura cross-coupling reaction catalyzed using highly efficient CN-dimeric ortho-palladated complex under microwave irradiation and conventional heating
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full textSuzuki-Miyaura cross-coupling reaction catalyzed using highly efficient CN-dimeric ortho-palladated complex under microwave irradiation and conventional heating
Suzuki cross-coupling reaction of different aryl halides with arylboronic acids was successfully carried out in methanol using ortho-palladated complex of 2-methoxyphenethylamine. All substrates afforded the corresponding products in good to high yields in the presence of low amounts of this complex as efficient and active catalyst. Application of microwave irradiation improved the yields of th...
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Journal title:
iranian journal of catalysisPublisher: islamic azad university, shahreza branch
ISSN 2252-0236
volume 2
issue 3 2012
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